Li2Ru0.6Mn0.4O3/氧化石墨烯复合材料的制备 及电化学性能
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Preparation and Electrochemistry Performance of Li2Ru0.6Mn0.4O3/ Graphene Oxide Composite
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    摘要:

    采用氧化石墨烯(Graphene oxide,GO)与固相法制备的Li2Ru0.6Mn0.4O3复合得到Li2Ru0.6Mn0.4O3/ GO复合电极材料,并利用X射线衍射(X-ray diffraction,XRD)、扫描电子显微镜(Scanning electron microscope,SEM)、透射电子显微镜(Transmission electron microscope, TEM)和能谱仪(Energy dispersive spectrometer, EDS)分别对其晶体结构、形貌进行了表征。氧化石墨烯不仅可以改善Li2Ru0.6Mn0.4O3的导电性,而且可减小其在电解液中因溶解而发生的副反应。电化学测试表明:复合后电极材料的循环性能和倍率性能得到了明显的改善,200圈以后容量依然为初始容量的87.5%;5 C大倍率的充放电后,电流密度回到0.1 C时,容量保持在初始容量的95%以上。

    Abstract:

    Li2Ru0.6Mn0.4O3/Graphene oxide(GO) composite material is obtained by mixing GO and the solid-state prepared Li2Ru0.6Mn0.4O3. The microstructure, morphology and electrochemical performances of product are analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive spectrometer (EDS) and electrochemical tests. Mildly oxidized graphene oxide mixing is found to improve the battery performance by enhancing the conductivity and protecting the cathode surface from undesired reactions with the electrolyte. The electrochemistry results show that the material exhibits better rate capacity than that of Li2Ru0.6Mn0.4O3 since the composite GO demonstrates the enhanced electronic conductivity. Accordingly, Li2Ru0.6Mn0.4O3/GO exhibits 87.5% capacity retention after 200 cycles in the cycling test, and at a large current of 5 C, Li2Ru0.6Mn0.4O3/GO is able to deliver 95% of the 0.1 C capacity.

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房新梅 米常焕 陶洪亮 张迎霞. Li2Ru0.6Mn0.4O3/氧化石墨烯复合材料的制备 及电化学性能[J].南京航空航天大学学报,2017,49(1):50-55

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  • 在线发布日期: 2017-03-02
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