Fe3O4对微波扫描快速成形复合材料固化速率及性能的影响
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Effect of Fe3O4 on Scanning Microwave Curing Rates and Performance of Epoxy Composites
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    摘要:

    为实现大型复合材料构件损伤的微波扫描固化快速修补,提出选择吸波性能优异的Fe3O4作为环氧E51+DDM体系的微波吸收剂,利用超声设备对Fe3O4粉体进行分散, 研究了Fe3O4添加量对微波扫描固化速度的影响并探索其增速机理;在此基础上制备Fe3O4体系的玻纤/环氧复合材料试验件,研究了添加Fe3O4对玻纤增强复合材料热、力学性能的影响。研究结果表明:Fe3O4的加入提高了体系的吸波能力进而加快体系的反应速率,且在添加量为1%时对体系的增速效率最高,与纯环氧体系相比其固化时间缩短了24%;与未加Fe3O4纯体系相比,添加1% Fe3O4环氧体系的玻璃化转变温度提高了1.5 ℃,拉伸模量提高了5.8%,但两者的拉伸强度相当,弯曲强度及短梁剪切强度分别提高了9.0%和6.5%。

    Abstract:

    In order to implement the rapid repair of damaged largescale composite component using the scanning microwave curing technology, Fe3O4 with good microwave-absorbing performance is chosen as the microwave absorber and the ultrasonic devices are used to disperse Fe3O4 powder in this paper. The effect of Fe3O4 dosage on the curing rate as well as the rate acceleration mechanism is studied. The composite with Fe3O4 epoxy system is prepared for further study and the influence of Fe3O4 on thermal and mechanical properties of glass fiber reinforced composites is studied too. Results show that Fe3O4 can improve the absorbing capacity of the system and thus accelerate the reaction rate. The highest growth rate is achieved with 1% dosage of Fe3O4 and can saved curing time by 24% compared with the pure system. Compared with the pure system without Fe3O4, the glass transition temperature of the counterparts with 1% dosage of Fe3O4 increases by 1.5 ℃, and tensile modulus is improved by 5.8%,whereas the tensile strength is almost the same. Furthermore, the bending strength and the short beam shear strength are improved by 9.0% and 6.5%, respectively.

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游彦宇 李勇还大军褚奇奕肖军周克印. Fe3O4对微波扫描快速成形复合材料固化速率及性能的影响[J].南京航空航天大学学报,2016,48(4):569-576

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  • 在线发布日期: 2016-09-08
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